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  • 學位論文

含N, N΄-二-(2-吡啶)己二醯二胺配位基 與過渡金屬化合物之化學研究

Chemistry of Transition Metal Complexes Containing N,N΄-di(2-pyridyl)adipoamide

指導教授 : 吳吉輝 陳志德
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摘要


經由過渡金屬化合物(AgNO3, AgClO4, Ag2SO4, Cu(ClO4)2, PtCl2, PdCl2, HgCl2)與配位基N,N΄-di(2-dipyridyl)adipoamide (H2DpyA) 的反應,得到了{[Ag(L)(NO3)]}∞ (1), {[Ag(L)(ClO4)]}∞ (2), {[Ag(L)(ClO4)]}∞ (3), {[Ag2(L2.5)(SO4)]}∞(4), {[Cu(L)(ClO4)2]}∞ (5), [PtLCl2] (6), [PdLCl2]•H2O (7) 與 [Hg2(L)(Cl)4] (8) 等八個錯化合物。此八個錯化合物的構造均已利用X-ray鑑定之,而經由X-ray解出的構造中,錯化合物1-5是配位高分子化合物;錯化合物6和7是含有金屬的環狀化合物;然而錯化合物8是一個雙核的金屬錯化合物。錯化合物1和3形成鋸齒狀的長鏈,而每條長練是經由Ag•••O的作用力和C-H•••O, N-H•••O的氫鍵作用力所連接起來。錯化合物2形成螺旋狀的長鏈,而每條長練是經由C-H•••Ag, Ag•••O的作用力和N-H•••O的氫鍵作用力所連接起來。錯化合物4形成餘弦波狀的長鏈,而每條長練是經由Ag•••O的作用力和C-H•••O的氫鍵作用力所連接起來。錯化合物5形成鋸齒狀的長鏈,而每條長練是經由Cu•••O的作用力和N-H•••O的氫鍵作用力所連接起來。錯化合物6和7則形成含有金屬的十三元環的環狀化合物,而每個分子是經由Pd•••Cl的作用力和C-O•••H, C-H•••Cl的氫鍵作用力所連接起來。錯化合物8形成一個雙核的金屬化合物,而每個分子是經由Hg•••O的作用力和C-H•••Cl的氫鍵作用力所連接起來。

並列摘要


A series of the transition metal complexes {[Ag(L)(NO3)]}∞ (1), {[Ag(L)(ClO4)]}∞ (2), {[Ag(L)(ClO4)]}∞ (3), {[Ag2(L2.5)(SO4)]}∞(4), {[Cu(L)(ClO4)2]}∞ (5), [PtLCl2] (6), [PdLCl2]•H2O (7), [Hg2(L)(Cl)4] (8) [where L= N,N΄-di(2-dipyridyl)adipoamide] have been prepared by the reactions of transition metal compounds (AgNO3, AgClO4, Ag2SO4, Cu(ClO4)2, PtCl2, PdCl2, HgCl2) with L. All the complexes have been structurally characterized by X-ray crystallography, confirming that 1-5 are coordination polymers whereas 6 and 7 are metalacycles, and 8 is a binuclear compound. Complexes 1 and 3 form zigzag chains which are interlinked through a series of Ag•••O interactions and C-H•••O and N-H•••O hydrogen bonds. Complex 2 forms helical chains which are interlinked through a series of C-H•••Ag and Ag•••O interactions and N-H•••O hydrogen bonds. Complex 4 forms cosine wave chain which are interlinked through a series of Ag•••O interactions and C-H•••O hydrogen bonds. Complex 5 forms zigzag chains which are interlinked through a series of Cu•••O interactions and N-H•••O hydrogen bonds. Complexes 6 and 7 form thirteen-members rings which are interlinked through a series of Pd•••Cl interactions and C-O•••H and C-H•••Cl hydrogen bonds. Complex 8 forms binuclear complexes which are interlinked through a series of Hg•••O interactions and C-H•••Cl hydrogen bonds.

參考文獻


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