含多重氫鍵金屬化合物之研究

Study on Metal Complexes Containing Self-Complementary Multiple Hydrogen Bonds

許漢宇(Han-Yu Hsu)

指導教授 ： 陳志德 ； 謝博進

中原大學/理學院/化學研究所/碩士(2004年)

https://doi.org/10.6840/cycu200400198

摘要

中文摘要

此篇論文主要在探討包含多重氫鍵過渡金屬錯化合物之超分子化學。

四個含2-dipyrimidylamine (dipm) 配位基之二價金屬錯化合物Zn(NO3)2(dipm)(CH3OH), 1；Mn2Cl4(dipm)2(CH3OH)2, 2； Fe2Cl4(dipm)2(CH3OH)2, 3 ； FeCl2(dipm)2(CH3OH)2, 4，可經由金屬起始物Zn(NO3)2．6H2O, MnCl2．H2O, FeCl2及 FeCl2．4H2O與配位基 dipm 於甲醇下反應得到，其結構均已被X-ray鑑定及分析。化合物1及4 為單核而化合物2及3為雙核之錯合物，此四個金屬錯合物皆具有以D (donor) –A (acceptor) –D (donor) –A (acceptor)多重氫鍵形式鍵結之特徵。

關鍵字

多重氫鍵 ； 自我組合 ； 超分子化學

並列摘要

Abstract

Four transition metal complexes containing the ligand 2-dipyrimidylamine (dipm), Zn(NO3)2(dipm)(CH3OH), 1； Mn2Cl4(dipm)2(CH3OH)2, 2；Fe2Cl4(dipm)2(CH3OH)2, 3 and FeCl2(dipm)2(CH3OH)2, 4, were synthesized and structurally characterized. The metal complexes were prepared by reactions of dipm with Zn(NO3)2．6H2O, MnCl2．H2O, FeCl2 and FeCl2．4H2O, respectively, in CH3OH. Complexes 1 and 4 are mononuclear while 2 and 3 are dinuclear complexes. All the molecules of the four complexes are interlinked through D (donor)–A (acceptor)–D (donor)–A (acceptor) self-complementary multiple hydrogen bonds.

並列關鍵字

Multiple Hydrogen Bonds ； Self-Complementary ； Supramolecular Chemistry

參考文獻

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