In this study, polyamide (PA) film was casted by twin screw extruder and followed by bi-axially stretching. In the first part, the thermal properties were analyzed by measuring the heat flow in the adiabatic process by using differential scanning calorimetry (DSC). In the second part, the properties of BOPA film were analyzed including optical properties and oxygen transmission rate (OTR), and the relationship among the stretching process and the grades of nylon.