中文摘要 本論文主要探討含多芽氮配位基與一價銀金屬及二價銅金屬化合物之化學。 使用一價銀金屬化合物AgX (X = NO3{, ClO4{, BF4{和PF6{);及二價銅金屬化合物Cu(O2CCH3)2與配位基2-amino-4-methylpyrimidine (amp) 在甲醇/水溶液下反應,可以得到下列五種新型化合物:[Ag(amp)2](NO3), 1 ; [Ag(amp)2](ClO4), 2 ; [Ag(amp)2](BF4), 3 ; [Ag(amp)2](PF6), 4及[Cu2(O2CCH3)4(amp)2], 5,以上所有化合物的結構皆由X-ray單晶繞射儀鑑定出。 化合物1{4中每個銀原子以橋接的形式與兩個amp嘧啶環上的氮原子鍵結,而在化合物5中兩個amp配位基分別接在Cu2(O2CCH3)4化合物的軸向位置上。 化合物1{5中,其分子皆以成對的N{H---N自我互補氫鍵﹙Self-complementary double hydrogen bonding﹚連結形成一維的鏈狀化合物。
A series of silver (I) complexes of the types [Ag(amp)2](NO3), 1 ; [Ag(amp)2](ClO4), 2 ; [Ag(amp)2](BF4), 3 ; [Ag(amp)2](PF6), 4 and [Cu2(O2CCH3)4(amp)2], 5 have been prepared by the reactions of AgX (X = NO3{, ClO4{, BF4{, PF6{) and Cu(O2CCH3)2 with amp (amp = 2-amino-4-methylpyrimidine) in methanol solution. All the complexes have been structurally characterized by X-ray crystallography , FT-IR and 1H-NMR spectra. The molecules of complex 1–5 are interlinked through a series of self-complementary double hydrogen bondings to form one –dimensional molecular chains.