Piptocephalis (Piptocephalidaceae, Zoopagales, Zoopagomycetes, Zoopagomycotina, Zoopagomycota) is a genus of mycoparasitic, haustorium-forming fungi and can usually be isolated from soil, dung and leaf litters ubiquitously. Piptocephalis chienii, a new mycoparasite of Cunninghamella bertholletiae, has been isolated from forest soil in Taiwan. It is characterized by an erect main sporophore, which produces a fertile system comprising five successive dichotomously branching sporophores. The sporophores are smooth and perforated with a projecting pore. The head cells are obconical and deciduous, bearing six merosporangia with 3-4 spores each. The spores are cylindrical, smooth-walled, and the spore head is dry at maturity. The zygospore wall has a rugulose reticulate ornamentation. This new species is compared with other related taxa, and an identification key to the known species of Piptocephalis is provided.