This study used data from an online dating site to examine the effects of educational mating preference on marriage opportunities using a two-side matching simulation approach. We found that higher-educated women and lowereducated men have the lowest marriage opportunities among all educational groups. This may be one of the important reasons why these two educational groups have the lowest marriage rate in their gender. Furthermore, through different types of simulation, we found that even setting wider educational thresholds would not lead higher-educated women's and lower-educated men's marriage opportunities to increase. Only when the opposite genders set lower ceiling-educational thresholds could their marriage opportunities increase. The key factor for increasing marriage opportunities is not in their own hands.