Nowadays, the preparation of waterborne polyurethane in industries usually uses acetone processing method, in the synthesis process, a large amount of solvents is often used, moreover, the acetone method consumes more energy and high equipment costs. Its volatile and flammable cause harm to the environment and operator safety, reducing volatile organic compounds have become a trend of green issues. Therefore, this research devoted to synthesis of solvent-free waterborne polyurethane, discussing its physical properties after film formation, and testing the performance of waterborne polyurethane after coating.