In this study, we synthesized 7 kinds of 3-(N,N-diethylamino)propanilide disperse dyes and the structure of the dyes were determined by spectral analysis. When dyeing polyester (PET) fabrics in supercritical carbon dioxide, the relative dye uptake of dyes P1, P4, P5 and P7 were higher than 85%. Polyester (PET) fabrics were dyed in supercritical carbon dioxide, and the relative dye uptake of dyes P1, P4, P5 and P7 were higher than 85%. In addition, the dyeing fastness was tested by comprehensive international inspection standards. The results showed that the dyeing fastness of dyes P4, P5 and P7 met commercial standards and were suitable for supercritical carbon dioxide to dye polyester (PET) fabrics.