The purpose of this paper is to develop an approach to a network structure which considers the two factors: link, intermediate. Furthermore, we categorize intermediate activities into four types, i.e. desirable, undesirable, discretionary and nondiscretionary. We will analysis a decomposed network and integrated approach based on data envelopment analysis (DEA) on the basis of slack-based measure (SBM). Firstly, classifying the network structure into three stages; secondly, opening the black box to obtain the period efficiency; lastly, it allows us to integrate the efficiency value of a DMU at all stages. An example is used to be done for efficiency evaluation about coke production chain of twelve provinces of China.