In daily communication or work, employees need to adjust their emotions according to the rules and show the emotional state satisfying the organization. Based on the theory of resource conservation, this paper discusses the influence mechanism of surface acting and deep acting on employees' deviant behavior. The results show that surface acting and deep acting will affect employees' deviant behavior; Emotional exhaustion plays a mediating role between surface acting, deep acting and employees' deviant behavior. The perceived organizational support has a moderating effect on the relationship between emotional exhaustion and employees' deviant behavior. The research results enrich the theoretical model of emotional labor, and enterprises can take appropriate intervention measures to alleviate the emotional exhaustion and deviant behavior of employees caused by surface and deep acting.