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  • 學位論文

非晶矽/單晶矽異質接面太陽能電池

a-Si:H/c-Si Heterojunction Solar Cells

指導教授 : 李嗣涔

摘要


在本論文中,首先探討非晶矽薄膜在140℃下成長時的結構、光學及電學特性。使用氫氣稀釋比例Xg=0.66 作為非晶矽/單晶矽異質接面太陽能電池的成長參數。接著利用電壓-電流特性曲線量測 非晶矽/單晶矽 異質接面特性。為了改善 p型非晶矽/ n型單晶矽介面,選擇兩種方法來達到此目的。插入一層本質非晶矽薄膜在p型非晶矽/ n型單晶矽介面不但降低漏電流並且改善了填充因子。此外使用電漿處理的方法在單晶矽表面上也改善p型非晶矽/ n型單晶矽介面並且讓開路電壓提升至0.58伏特。最後為了提升短路電流,藉由成長一層n型重參雜非晶矽薄膜在晶圓背面來達成背表面電場(BSF)結構。太陽能電池特性為開路電壓( Voc=0.58伏特)、短路電流(Jsc=33.2 毫安培/平方厘米)、最大輸出功率(Pmax=11.45毫瓦/平方厘米)、填充因子(F.F.=0.595)、轉換效率11.45%。

並列摘要


In this thesis, the structure, optical and electrical properties of the hydrogenated amorphous silicon ( a-Si:H ) thin films which is fabricated under 140℃ are investigated first. The hydrogen dilution ratio Xg=0.66 is chosen for proper deposition parameter to fabricate a-Si:H/c-Si heterojunction solar cells. Then (i)a-Si/ (n)a-Si hetrojunction is studied by means of current-voltage characteristics measurement. In order to improve (p)a-Si:H/ (n)c-Si interface, two ways are chosen to achieve this goal. Insert an intrinsic a-Si:H at (p)a-Si:H/ (n)c-Si interface not only reduces the leakage current but also improves fill factor. Besides, implement plasma treatment on c-Si surface also improve a-Si:H/ c-Si interface and the open circuit voltage ( Voc ) is increased to 0.58. Finally, in order to increase short circuit current ( Jsc ), back surface field ( BSF ) structure is introduced by means of adding n+ layer at back side of silicon wafer. The solar cell performance is open circuit voltage ( Voc=0.58V ), short circuit current density ( Jsc=33.2mA/cm2 ), maximum output power ( Pmax=11.45mW/cm2 ), fill factor ( F.F.=0.595 ) and efficiency=11.45%.

並列關鍵字

a-Si heterojunction solar cell

參考文獻


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