透過您的圖書館登入
IP:216.73.216.250
  • 學位論文

利用超音波震盪器分散液體中奈米銀顆粒液

Mechanical dispersal of silver nanopowder in water using ultrasonic atomizer

指導教授 : 鍾清枝

並列摘要


Nanoparticles have been widely applied into many fields of science, industry, and medicine, etc. However, agglomeration of nanoparticles always exists in every application involving nanoparticles, it strongly reduces the function of nanoparticles and becomes a big challenge. In this research dispersion was focused studied to solve the problem of nanoparticle agglomeration by original mechanical way, which has been considered as extremely difficult. The study proposed two new dispersing methods, where ultrasonic atomizer with the frequency of 1.6 MHz was used as dispersing apparatus. These dispersals were also compared to the well known conventional dispersals such as ultrasonic cavitation (20 kHz) and sonication bath (19 kHz) to evaluate the dispersing function of proposed dispersals. Dynamic light scattering, scanning electron microscope and transmission electron microscope were utilized to study distribution behavior of silver nanoparticles in colloid after dispersal. The experimental results indicated that, two proposed dispersing methods dispersed silver nanoparticles (25 nm in diameter) very homogeneously in water at room temperature with the small average size of dispersed particles (up to 100 nm) and narrow particle size range, a result is much better than that of two conventional dispersals. Moreover, colloids dispersed by two proposed methods were very stable with zeta-potential factor approximated or over 30 mV – stable level of colloid

參考文獻


[1] J.P. Wilcoson, J.E. Martin, Photoluminescence from nanosize gold clusters, J. Chem. Phys. 108 (1998) 9137-9143
[2] Y. Hayashi, H. Takizawa, M. Inoue, K. Niihara, K. Suganuma, Ecodesigns and application for noble metal nanoparticles by ultrasound process, IEEE Trans. Electron. Packaging Manufact. 28 (2005) 338-343
[3] V.Jokanovi’c, A.M. Spasi’c, D. Uskokovi’c, Designing of nanostructured hollow TiO2 spheres obtained by ultrasonic spray pyrolysis, J. Colloid Interface Sci 278 (2004) 342 -352
[4] A. Gedanken, Doping nanoparticles into polymers and ceramics using ultrasound radiation, Ultrason. Sonochem.14 (2007) 418-430
[5] Y. Zhou, F. Pervin, L. Lewis, S. Jeelani, Fabrication and characterization of carbon/epoxy composites mixed with multi-walled carbon nanotubes, Mater. Sci. Eng. A xxx (2007) , doi:10.1016/j.msea.2007.04.043

延伸閱讀