中紅外光穿透性鈣鋁酸鹽玻璃陶瓷性質探討

Properties of Middle IR Transmitting Calcium Aluminate Glass-Ceramics

許神豪(Shen-Hao Hsu)

指導教授 ： 徐錦志

大同大學/工程學院/材料工程學系所/碩士(2008年)

摘要

鈣鋁酸鹽玻璃在中紅外光波長 (3 – 5 μm)範圍具有良好的穿透率以及機械性質。製成玻璃陶瓷後可提昇機械強度，使應用更廣。本實驗於含ZrO2可形成鈣鋁酸鹽玻璃陶瓷的成份中，分別添加GeO2、SiO2、Y2O3、La2O3、Sb2O3並探討其影響。結果發現，各成份玻璃陶瓷的可見光穿透率以添加Sb2O3最低，添加Y2O3最高。紅外光穿透率則以添加GeO2、SiO2較低，添加Y2O3、La2O3、Sb2O3較高。整體性質的表現，以添加Y2O3最穩定。

關鍵字

中紅外光穿透性材料 ； 鈣鋁酸鹽玻璃陶瓷

並列摘要

Calcium aluminate glasses (CAG) have good optical transmittance in the middle infrared (3 – 5 μm) range and good mechanical properties. Transforming CAG into glass-ceramics could enhance its mechanical properties and may broaden its application field. In this study, effects of the addition of GeO2, SiO2, Y2O3, La2O3, Sb2O3 on ZrO2 – nucleated calcium aluminate glass-ceramic are studied.. According to the experimental results, for glass ceramic optical transmittance in visible light, adding extra Y2O3 content can obtain the maximum and adding Sb2O3 can obtain the minimum of efficiency. For glass ceramic optical transmittance in infrared , adding extra Y2O3, La2O3 or Sb2O3 content can obtain the maximum and adding GeO2 or SiO2 can obtain the minimum of efficiency. For the whole considerations, adding extra Y2O3 content has the best stability to glass-ceramics.

並列關鍵字

Calcium Aluminate Glass-Ceramics ； Middle IR Transmitting Material

參考文獻

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