The low phosphorus content requirement is essential for production of the high-grade steel. It is great challenge to effectively dephosphorize during BOF (Basic Oxygen Furnace) slagging operation and to improve production efficiency and cost savings. In this study, we developed a double slag process and applied in the steelmaking operation practices. The lime dissolving mechanism and slagging process were analyzed. The modified processes based on the analysis results are successful for production of [P] <50ppm low phosphorus steel. Desiliconization slagging and deslagging technology was used in the newborn single blast of Dragon Steel with high silicon hot metal. The benefits of the newly developed process include: (1) rapid slagging reaction improving dephosphorization efficiency during BOF initial blowing period; (2) successfully reducing the amount of waste dumping hot metal; and (3) significant cost savings of BOF operation.