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Ambient-Pressure Synthesis of Superconducting YBa2Cu4O8

並列摘要


A highly homogeneous and monophasic high-T, superconductor YBa2Cu40a with Tc(zero) of 75 K and fine grain size has been synthesized at 1 atm of oxygen via a route employing polymeric ethylene glycol/citric acid (EG/CA) precursors. In addition to the chemistry involved in the preparation, the effect of preparation temperature, time of processing and EG/CA ratio in the precursor on the formation and superconductivity of the 124 phase was systematically investigated. The results of X-ray diffraction, the temperature dependence of resistivity and dc magnetic susceptibility, and the SEM microstructure studies on 124 synthesized under different conditions were also summarized.

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