The photovoltaic responses of a solid-state photovoltaic cell with structure TiO2/C60/CuSCN/, by electro-depositing C60 onto glass substrates comprised of nanocrystalline TiO2 films and subsequently chemically depositing CuSCN on to the above C60 film, were investigated. The device delivered a short-circuit photocurrent of 225 μA cm^(−2) with an open circuit voltage of 350 mV under an irradiance of 260 Wm^(−2). The charge transferring mechanism is described as the formation of a C60 anion from the excited C60 molecule by donating a hole to CuCNS and then, injecting the electron from the C60 anions into the conduction band of TiO2.