As the Internet and digital information technology has made a huge progress, e-learning and MOOCs recently become modern trends. This article explores new developments in e-learning and libraries participating in and some new services. Firstly, it examines how distance education was transferred into elearning, and definition, elements and new development of e-learning; secondly, it investigates the features and models of the MOOCs; thirdly, it discusses how e-learning extends library services and what is distance learning library services and their content. Finally, three cases studies on library e-learning services were provided with detailed description and examined based on the above new services theory and practices.