In this research it is aimed to investigate the characteristics of the microstructures and mechanical properties of high silicon ductile irons with alloying molybdenum. The results show that: (1) For high silicon ductile irons with molybdenum alloying, eutectic carbide containing molybdenum existed in the intercellular regions together with fine particles of carbide precipitated along its outer vicinity, those fine particles precipitated areas have a molybdenum concentration over 2.0wt.%; (2) The high temperature tensile strength of high silicon ductile irons increase with the increasing of molybdenum content, that strengthening effect could be attributed to the strengthening in the ferrite matrix from molybdenum and intercellular eutectic carbide; (3) The amount of intercellular eutectic carbide increased with the increasing of molybdenum content, and then tended to form network structure. Relatively, these intercellular eutectic carbides did not have strong effect on the mechanical properties in room temperature when comparing to the influence of silicon.