This study analyzes the relationship between NT Build 492 Rapid Chloride Migration test (RCM) and salt ponding test to assess the concrete diffusion coefficient in marine environment. In addition, NT Build 492 RCM has some problems in colorimetric method and theoretic model. The experimental results have a high coefficient of variation. Therefore, the two-sample method is used to determine the actual chloride profile. Comparing the RCM and chloride profile after RCM, it shows the difference between the traditional theoretic model and actual chloride profile. Therefore, the new migration model is developed in this study. The result of modified RCM model shows a good linear relationship existed between migration coefficient and diffusion coefficient.