Most Value at Risk models use close price to calculate the risk measure. This paper proposes a new approach to calculate Value at Risk using open-close and high-low prices information. We further apply our model in the application of portfolio VaR. Our approach is based on Hull and White (1998) model and incorporates open-close and high-low prices to adjust volatility measure. Using eight stocks traded in Taiwan markets, the empirical study shows that our approach can improve the performance of Value at Risk models in general.