In this study, N-methylpyrrolidone (NMP) was used to dissolve polyvinylidene fluoride (PVDF) to prepare an electrospinning solution, and graphene oxide (GO) was added for mixing to discuss functional groups, surface morphology, and contact angles, Resistivity and electrical performance, and evaluate the ion exchange effect applied to the battery. The research shows that compared with the film without graphene oxide (GO), the research has achieved a resistivity rise to 1.62%, a voltage rise to 0.12V, ampere The index rose to 3.42% and the power rose to 1.14%, indicating that the addition of polyvinylidene fluoride (PVDF) spinning solution to graphene oxide GO can effectively improve battery efficiency.