I adopt one of Kant's important moral perspectives to comprehend and reinterpret Mencius' philosophy. That is "our cognition of unconditional practice must start from unconditional law." In Mencius' moral theory, he starts from the function of moral mind (free will) to define the nature of human. Based on his arguments of "possessing moral mind is being qualified for man to be a human" and "the value-based distinction between human and animal", he reveals the meanings of moral mind. One of Mencius' theses of moral mind is similar to Kant's theses of free will. Kant, on the basis of moral law which is the fact of reason, analyzes the meanings of morality. With regard to the result of Kant's analysis, Mencius shares some similarities with Kant. This proves that it is feasible to claim that starting from free will can justify how unconditional moral practice is possible. Mencius's approach to understanding and defining the nature of human is in such way. However, Kant disapproves of the perspective on starting from free will to justify how unconditional moral practice is possible. Through clarifying the above questions, we can see the similarities and dissimilarities between Mencius and Kant.