In this study, thermochromic materials of [(CH3CH2)2NH2]2[CuCl4] ]percentage concentration of 0.2wt% by weight added to PVA solution (4wt%) and by the weight percent concentration (0.1wt%, 0.15wt%, 0.2 wt%) adding zinc oxide thin films made in the film were irradiated UV / Vis spectrometer and the spectral analyzer, the results obtained by adding thermochromic oxide films with the absorption350nm-200nm of alcohol ultraviolet shielding effect, and with the temperature will increase the value of increased absorption, transmittance decreases.