Isolation and Identification of Steroidal Saponins in Taiwanese Rhizoma Paridis Cultivar (Paris formosana Hayata)

台灣蚤休(Paris formosana Hayata)類固醇皂苷的分離與鑑定

楊登傑(Deng-Jye Yang) ； 張耀仁(Yan-Zin Chang) ； 劉世詮(Shih-Chuan Liu) ； 呂美鵬(Mei-Peng Lu) ； 林昭田(Jau-Tien Lin)

《臺灣農業化學與食品科學》 48卷6期 (2010/12) Pp. 289-300

https://doi.org/10.6578/TJACFS.2010.034

摘要

台灣蚤休(Paris formosana Hayata)具有九個類固醇皂苷，其化學結構是利用液－液萃取配合高效能液相層析儀進行分離純化，再經液相層析質譜儀與核磁共振儀進行結構鑑定得知。此九個類固醇皂苷包括三個furostanol glycosides: 26-O-β-D-glucopyranosyl-22α-methoxyl-(25R)-furost-5-en-3β, 26-diol 3-O-α-L-rhamnopyranosyl-(1→4)-O-α-L-rhamnopyranosyl-(1→4)-O-[α-L-rhamnopyranosyl-(1→2)]-β-D-glucopyranoside, 26-O-β-D-glucopyranosyl-22α-methoxyl-(25R)-furost-5-en-3β, 26-diol 3-O-α-L-rhamnopyranosyl-(1→2)-O-[α-L-arabinofuranosyl-(1→4)]-β-Dglucopyranoside和26-O-β-D-glucopyranosyl-22α-methoxyl-(25R)-furost-5-en-3β, 26-diol 3-O-α-L-rhamnopyranosy-(1→2)-O-[β-D-glucopyranosyl (1→3)]-β-D-glucopyranoside, 二個pennogenyl glycosides (spirostanol glycosides): 25 (R)-spirost-5-en-3β, 17-diol 3-O-α-L-rhamnopyranosy-(1→4)-O-α-L-rhamnopyranosyl-(1→4)-O-[α-L-rhamnopyranosyl-(1→2)]-β-Dglucopyranoside和(25R)-spirost-5-en-3β, 17-diol 3-O-α-L-rhamnopyranosyl-(1→2)-[α-L-arabinofuranosyl-(1→4)]-β-D-glucopyranoside以及四個diosgenyl glycosides (spirostanol glycosides): (25R)-spirost-5-en-3β-ol 3-O-α-L-rhamnopyranosyl-(1→4)-O-α-L-rhamnopyranosyl-(1→4)-O-[α-L-rhamnopyranosyl-(1→2)]-β-D-glucopyranoside, 3-O-α-L-rhamnopyranosyl-(1→2)-[β-D-glucopyranoside-(1→3)]-β-D-glucopyranoside, (25R)-spirost-5-en-3β-ol 3-O-α-L-rhamnopyranosyl-(1→2)-[α-L-arabinofuranosyl-(1→4)]-β-D-glucopyranoside (25R)-spirost-5-en-3β-ol和(25R)-spirost-5-en-3β-ol 3-O-α-Lrhamnopyranosyl-(1→2)-O-β-D-glucopyranoside.

關鍵字

蚤休 ； Paris formosana Hayata ； furostanol glycoside ； spirostanol glycoside ； pennogenin ； diosgenin

並列摘要

台灣蚤休(Paris formosana Hayata)具有九個類固醇皂苷，其化學結構是利用液－液萃取配合高效能液相層析儀進行分離純化，再經液相層析質譜儀與核磁共振儀進行結構鑑定得知。此九個類固醇皂苷包括三個furostanol glycosides: 26-O-β-D-glucopyranosyl-22α-methoxyl-(25R)-furost-5-en-3β, 26-diol 3-O-α-L-rhamnopyranosyl-(1→4)-O-α-L-rhamnopyranosyl-(1→4)-O-[α-L-rhamnopyranosyl-(1→2)]-β-D-glucopyranoside, 26-O-β-D-glucopyranosyl-22α-methoxyl-(25R)-furost-5-en-3β, 26-diol 3-O-α-L-rhamnopyranosyl-(1→2)-O-[α-L-arabinofuranosyl-(1→4)]-β-Dglucopyranoside和26-O-β-D-glucopyranosyl-22α-methoxyl-(25R)-furost-5-en-3β, 26-diol 3-O-α-L-rhamnopyranosy-(1→2)-O-[β-D-glucopyranosyl (1→3)]-β-D-glucopyranoside，二個pennogenyl glycosides (spirostanol glycosides): 25 (R)-spirost-5-en-3β, 17-diol 3-O-α-L-rhamnopyranosy-(1→4)-O-α-L-rhamnopyranosyl-(1→4)-O-[α-L-rhamnopyranosyl-(1→2)]-β-D-glucopyranoside和(25R)-spirost-5-en-3β, 17-diol 3-O-α-L-rhamnopyranosyl-(1→2)-[α-L-arabinofuranosyl-(1→4)]-β-D-glucopyranoside以及四個diosgenyl glycosides (spirostanol glycosides): (25R)-spirost-5-en-3β-ol 3-O-α-L-rhamnopyranosyl-(1→4)-O-α-L-rhamnopyranosyl-(1→4)-O-[α-L-rhamnopyranosyl-(1→2)]-β-D-glucopyranoside, 3-O-α-L-rhamnopyranosyl-(1→2)-[β-D-glucopyranoside-(1→3)]-β-D-glucopyranoside, (25R)-spirost-5-en-3β-ol 3-O-α-L-rhamnopyranosyl-(1→2)-[α-L-arabinofuranosyl-(1→4)]-β-D-glucopyranoside (25R)-spirost-5-en-3β-ol和(25R)-spirost-5-en-3β-ol 3-O-α-Lrhamnopyranosyl-(1→2)-O-β-D-glucopyranoside.

並列關鍵字

Rhizoma Paridis ； Paris formosana Hayata ； furostanol glycoside ； spirostanol glycoside ； pennogenin ； diosgenin