Isotherm, Thermodynamic and Kinetic Studies of Selective CO_2 Adsorption on Chemically Modified Carbon Surfaces

Adedeji Adebukola Adelodun ； Jane Catherine Ngila ； Do-Gun Kim ； Young-Min Jo

《Aerosol and Air Quality Research》 16卷12期 (2016/12) Pp. 3312-3329

https://doi.org/10.4209/aaqr.2016.01.0014

摘要

Detailed assessments of adsorption properties (isotherm, thermodynamics and kinetics) were carried out on chemically modified activated carbon (AC). Some pretreatment methods prior amination have been used to improve the CO_2 selective capture of AC in our previous works. Here, the inter-relationships among the adsorption properties were further investigated and reported. It was found that CO_2 molecules bind onto the heterogeneous surfaces of AC in a monolayer pattern as experimental data fit Freundlich isotherm rather than Langmuir. However, Redlich-Peterson, a 3-parameter model provided the best fit. The highest degree of precision of Chi-square analysis professed it as the most efficient error function for the isotherm study. Values of standard entropy showed to be the most significant thermodynamic limiting parameter in the adsorption process, as physisorption was found predominant for CO_2 collection at the interface. This observation was corroborated with temperature programmed desorption (TPD) analysis where ca. 86% of adsorbed CO_2 were desorbed below 500°C. The kinetic study indicated that CO_2-AC interaction follows pseudo-second order while the higher R^2 of intraparticle diffusion over Elovich equation confirmed the deduction made from the thermodynamic study. Conclusively, the study of adsorption properties in this work provides useful information for designing proper adsorption reactor and subsequent regeneration of CO_2-laden adsorbents at environmental levels.

關鍵字

Activated carbon ； Adsorption selectivity ； Isotherms ； Thermodynamics ； Kinetics