Characteristics of Air Pollutants and Greenhouse Gases at a Regional Background Station in Southwestern China

Linjun Cheng ； Dongsheng Ji ； Jun He ； Liang Li ； Li Du ； Yang Cui ； Hongliang Zhang ； Luxi Zhou ； Zhiqing Li ； Yingxin Zhou ； Shengyuan Miao ； Zhengyu Gong ； Yuesi Wang

《Aerosol and Air Quality Research》 19卷5期 (2019/05) Pp. 1007-1023

https://doi.org/10.4209/aaqr.2018.11.0397

摘要

The characteristics of air pollutants and greenhouse gases at regional background sites are critical to assessing the impact of anthropogenic emissions on the atmospheric environment, ecosystems and climate change. However, observational studies are still scarce at such background sites. In this study, continuous hourly observations of air pollutants (O_3, CO, SO_2, NO_x, PM_(2.5) and PM_(10)) and greenhouse gases (CO_2, CH_4 and N_2O) were performed for one year (from January 1 to December 31, 2017) at the Gongga Mountain background station (GGS; 101°97'E, 29°55'N; elevation: 3541 m) in southwestern China. The concentrations and variations of these air pollutants and greenhouse gases were determined, and the effect of transboundary atmospheric transport on the air pollution at the study site was investigated. The results showed that the average annual concentrations (mixing ratios) of the O_3, CO, SO_2, NO_2, CO_2, CH_4, N_2O, PM_(2.5) and PM_(10) were 74.7 ± 22.0 μg m^(-3), 0.3 ± 0.2 mg m^(-3), 0.5 ± 0.6 μg m^(-3), 1.7 ± 1.3 μg m^(-3), 406.1 ± 9.5ppm, 1.941 ± 0.071ppm, 324.5 ± 14.8 ppb, 6.5 ± 6.2 μg m^(-3) and 10.6 ± 11.2 μg m (-3), respectively. The concentrations (mixing ratios) of the abovementioned substances at the GGS are comparable to those at other background sites in China and around the world. The slight differences among concentrations at different sites may be mainly attributable to the impacts of anthropogenic emissions near the background sites and meteorological conditions. High values of O_3 were observed in spring and summer, while SO_2 and PM_(2.5) showed higher concentrations in summer than in autumn. Relatively high CO, NO_2 and PM_(10) values were mostly observed in spring and winter. Relatively low CO_2 concentrations were observed in summer due to the vigorous summertime photosynthesis of vegetation. The lowest concentrations for CH_4 were recorded in summer, whereas the levels in the other three seasons were similar to each other; by contrast, the highest N_2O concentrations were observed in summer due to enhanced microbial activity resulting from high ambient summer temperatures. A diurnal variation in O_3 was observed, with early morning minima and afternoon maxima. CO and NO_2 displayed higher concentrations in the daytime than in the nighttime. A slight increase in both PM_(2.5) and PM_(10) concentrations was also recorded in the daytime. These patterns were closely related to scattered anthropogenic emissions and regional atmospheric transport. Nevertheless, CO_2 exhibited lower concentrations in the daytime than in the nighttime, although CH_4 showed no obvious diurnal variation. The N_2O concentration peaked between 10:00 and 12:00 (local time), which can be ascribed to the enhancement of microbial activity due to the increased soil temperature. The results based on the relationship between the wind and the concentrations of air pollutants and greenhouse gases were almost consistent with those based on the potential contribution source function. It appears that O_3 and its precursors in parts of Inner Mongolia and Gansu, Ningxia, Sichuan, Chongqing and Hubei Provinces as well as adjacent areas of Hunan, Guizhou and Guangxi Provinces contributed to the increase in O_3 at the study site. The potential source areas for CO and SO_2 were similar and mainly distributed in India and Pakistan and areas of Inner Mongolia and Gansu and Guizhou Provinces in China. Potential source areas for NO_2, PM_(2.5) and PM_(10) were found in neighboring countries of South Asia in addition to domestic regions, including Inner Mongolia, Gansu Province and the Cheng-Yu economic region. Furthermore, parts of Yunnan Province (China) as well as India and Pakistan were potential source areas for CO_2, CH_4 and N_2O.

關鍵字

Air pollutants ； Greenhouse gases ； Background station ； Southwestern China