The paper explored the authentic experience of the first-time volunteering service of the hospice volunteers with the qualitative research method. We have recruited 11 hospice volunteers from a hospice volunteering team in a hospital in Beijing, using semi-structured interviews and material collection to collect data. Four themes includingstressful experience, comfort experience, benefit experience, and coping strategies for stressful experiences were extracted finally. Hospice volunteering service can have a positive impact on hospice volunteers, so we should promote more publicity. Hospice volunteer organizations should provide targeted support and education for the psychological pressure of hospice volunteers in their first volunteering service.