License Plate Recognition System (LPRS) divides into three parts: License Plate Location Finding (LPLF), Character String Segmentation, Enhancement (CSSE), and Character Recognition (CR). And they influence each other. Any part of them with distortion will severely decrease the efficiency of LPRS. In this paper, we use the learning ability of Artificial Neural Networks (ANN) to identify the number of car license plate quickly and correctly. We build the system consisted of orientation module and recognition module. The orientation module will pre-process the image, and scan the plate horizontally to find the boundary. Then scan the plate vertically and do the procedure of CSSE. The recognition module will use ANN of weighting value to train and learn to identify the license plate number to increase the percentage of recognition success.