The evaluation of pesticide residues in the raw materials of traditional Chinese medicines (TCM) is essential for the quality control of TCM. In this study, the contents of pesticides in 9 raw materials of TCM, including Corni Fructus, Cyathulae Radix, Glehniae Radix, Carthami flos, Schizonepetae Herba, Forsythiae Fructus, Artemisiae Scopariae Herba, Polygalae Radix, and Pogostemonis Herba were investigated. Twenty samples were tested for each raw material, making up a total of 180 samples. The residues of 229 pesticides were analyzed by GC/MS/MS and LC/MS/MS. The results showed that the contents of organochloride pesticide residues in all 180 samples complied with the regulatory limit. However, 17 samples of Corni Fructus, 11 samples of Artemisiae Scopariae Herba, 6 samples of Carthami flos, 6 samples of Pogostemonis Herba, 4 samples of Schizonepetae Herba, 3 samples of Polygalae Radix and 1 sample of Glehniae Radix were found to contain pesticide residues. The results could be used as a reference for the regulatory authority.