The main theme of this research is to demonstrate the feasibility of combining the nanotechnology and precious metal refining industry. This integration is of great importance in both technological and environmental concern. The chemical reduction method for the synthesis of precious metal nanoparticles shows a promise technique in conjunction with the refining line. Nano-silver was chosen for this demonstration. The Ag(NH3)2^+ solution directly produced from the silver refining procedure was transferred into the system for the nanosynthesis. The silver nanoparticles suspension can then be prepared readily. Several material characterizations were conducted, including the determination of the particle size distribution of ca. 5~20 nm in diameters. The results provide definitive evidence on the successfulness of the technological integration. The green nanotechnology is believed to be the future trend of the nano-industry.