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Electrical Properties of a Lead-Free Perovskite Ceramic: Ba(Gd_(1/2)Nb_(1/2))O_3

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Polycrystalline Ba(Gd_(1/2)Nb_(1/2))O_3 was prepared using a high-temperature solid-state reaction method. X-ray diffraction analysis indicated the formation of a single-phase cubic structure having space group Pm3m. AC impedance plots as a function of frequency at different temperatures were used to analyse the electrical behaviour of the sample, which indicated the negative temperature coefficient of resistance character. Complex impedance analysis targeted non-Debye type dielectric relaxation. Frequency dependent ac conductivity data obeyed Jonscher's power law. The apparent activation energy was estimated to be 0.17 eV at 1 kHz.

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