We have established a novel method of inserting poly(3,4-ethylenedioxythiophene) (PEDOT) between the layers of V_2O_5 using a soft process of intercalation. The reaction takes place with the in situ polymerization of EDOT within the framework of crystalline V_2O_5 with different nominal EDOT/V_2O_5 ratios. The hybrids PEDOT/V_2O_5 exhibit a high electrical conductivity.