藉熱階測定電荷移轉型錯合物固－液相圖之研究

Study on the Solid-liquid Phase Diagram of Charge Transfer Complex by the Hot Stage

趙承琛(Chen-Shen Chao) ； 吳維煌(Wei-Whong Wu)

《化學》 55年3期 (1966/09) Pp. 113-116

https://doi.org/10.6623/chem.1966016

摘要

藉熱階(hot stage)測定法以苦味酸和1, 3, 5-三硝基苯各與α-萘醇，β-萘醇及萘配合而得六種電荷移轉型錯合物之兩系固一液相圖。本研究中，電荷移轉型錯合物之摩爾比均為1:1。

並列摘要

Six solid-liquid phase diagrams of binary charge transfer complex systems which consist of picric acid and 1,3, 5-trinitrobenzene combined respectively with α-naphthol, β-naphthol and naphthalene, are determined by the hot stage. The solidus and liquidus lines are found by thawing points and melting points, which are measured by gradual hearing of the mixture in the capillary tube on the hot stage, instead of ordinary cooling curve method. .Mole ratios of these charge transfer complex compounds are all 1: 1.