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核苷類化合物的插入電子束質譜研究

In-Beam Mass Spectral Studies of Nucleosides

摘要


利用派勒克斯玻璃及單心銅線做成延長之送樣器,使用插入電子束撞擊法(In-beam EI)及介體單離的技術(matrix isolation)可成功地觀測到核苷類化合物之分子離子及類分子離子,其強度在4~43%之間,這些質譜的品質與斷裂型式與其他緩和游離法類似,但本法簡便而無需添加配件,不失爲測定對熱不穩定化合物質譜之良好方法。

關鍵字

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並列摘要


An extremely simple and effective modification has been developed using a Joel MSD-300 mass spectrometer. By using in-beam EI method together with matrix isolation technique, molecular ions and quasi molecular ions of several nucleosides were obtained in 4-43 percent relative abundances. The qualities and fragmentation patterns of these mass spectra are comparable to those obtained by other soft ionization methods.

並列關鍵字

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