高分子載體觸媒

周澤川 ； 黃炳照

《化學》 46卷1期 (1988/03) Pp. 57-60

https://doi.org/10.6623/chem.1988011

摘要

本文描述高分子載體觸媒的發展及應用與此種觸媒在發發固定化均勻解媒的角色，全文介紹以高分子為戴體所開發之相轉移觸媒反應，碳氫化合物的氧化反應即均勻與非均勻相串級式反應系統，多步驟反應系統，旋光性反應系統等。高分子戴體觸媒，可簡化產品與觸媒之分離及回收，可製備多功能性觸媒，將數個反應步驟縮成一個反應，及製備具特殊功能之官能基觸媒。高分子戴體觸媒具有發展性。

並列摘要

The current development and applications of polymer supported catalyst were reported. The study of immobilized homogeneous catalysts on the polymer carrier was also briefly described. The polymer supported catalyst included the phase transfer catalyst, heterogenizing homogeneous catalyst for the oxidation of hydrocarbons, multi-step reaction catalysts, supported asymmetric catalysts and others. The advantages of polymer supported catalysts are (1) Recovery of catalyst and separation of products and catalyst being simple and easy. (2) Preparation a multi-step reaction catalyst and reducing the reaction steps. (3) Preparation of specific functional group or active site catalyst.