透過您的圖書館登入
IP:18.117.91.153
  • 期刊

碳簇的電化學研究

Electrochemistry of Fullerenes

摘要


碳簇的研究是近年新興的領域,不論在基礎研究和應用發展,都有豐碩結果,極受注目。我們首先說明了碳簇分子發現的經過、其物理性質和化學性質,並對其電化學性質做了完整的回顧。電化學性質的討論中,我們將其為第三類。第一類是溶液中的碳簇電化學性質:它有六個單電子且為可逆的還原反應,和一個多電子不可逆的氧化反應。第二類是薄膜碳簇的電化學性質:它不同於溶液中行為,是具有陽離子參雜進入薄膜的還原反應,且於再氧化時並不全部釋出。第三類是LB膜碳簇的電化學性質:在單層膜時,它的電化學行為類似於溶液中的表現,在多層膜時,它亦有薄膜時的電化學表現。

關鍵字

球烯 電化學 LB 膜 氧化還原

並列摘要


The novel carbon clusters has been the subject of intense scruting since the discovery of facle methods for its preparation. There has been considerable interest in fullerenes both in their physical and chemical properties and their potential applications. In this paper we reported the history of discover and general physicochemical properties of fullerenes and focused on the electrochemistry of fullerenes. There are three catagories of electrochemistry of fullerenes have been discussed. First catagory is fullerene s in solution which shows six successive steps of one electron reversible reduction and one irreversible oxidation with mutielectron transfer. Second catagory is fullerene films which shows cation doping into films when reduction and retention in the films after reoxidation. Third catagory is LB films of fullerene. The monolayer LB film shows electrochemical behavior similar with the fullerenes in solution. The multilayer LB films have doping and dedoping behavior similar with thin films of fullerene.

並列關鍵字

Fullerenes Electrochemistry LB Films Redox

被引用紀錄


周芳妃(2007)。電化學壓電晶體液體感測器研製與應用〔博士論文,國立臺灣師範大學〕。華藝線上圖書館。https://www.airitilibrary.com/Article/Detail?DocID=U0021-0204200815531519

延伸閱讀


國際替代計量