本文綜述了手俊季銨鹽類相轉移催化劑及其在不對稱催化反應(包括說基化、Michael 加成、羰基加成和氧化反應)中的應用,並對影響手性相轉移催化反應立體選擇性的因素和催化反應機理進行了討論。
Chiral quaternary ammonium salts as phase-transfer catalysts and their applications to asymmetric alkylation, Michael addition, 1,2-carbonyl addition and oxidation were reviewed with 34 references; The influence of various factors on the stereoselectivity in c hir叫phase-transfer catalytic react ions and the mechanism of asymmetric catalysis were also discussed.