- 期刊
亞喹啉醌胺類配位化合物及其錯化合物的合成與光譜探討
Synthetic and Spectral Studies of Iminoquinolinone-type Ligands and Their Complexes
並列摘要
The iminoquinolinone-type ligands (IQLO) were synthesized by condensing 4-alkylaminopenylamines or hydroxy aromatic amines with 8-hydroquinoline (8HQ) in the presence of an oxidizing agent. The yield of IQLO was different from the reactants and experimental results, the reaction of 4-alkylaminophenylarnines with 8HQ was proposed to proceed by oxidation of aromatic hydroxyamines with oxygen and gave IQLO in 83-98% yields. The metal complexes containing IQLO were synthesized , in addition, these complexes exhibited absorption bands at 581757 nm. Also, EA, UV and IR were used to characterize these complexes. Coordination occurs via the oxygen atom of the quinoneimine moiety and the nitrogen atom of the pyridine moiety, as suggested by the above results.
延伸閱讀
- 陳宜君（2004）。含胺-亞胺雙牙配位鎳錯合物催化烯烴聚合反應的胺取代基效應及反應機制的探討〔碩士論文，國立臺灣大學〕。華藝線上圖書館。https://doi.org/10.6342/NTU.2004.00972
- Yu, C. W. (2012). 喹唑啉酮類化合物作為組蛋白去乙醯脢抑制劑之設計合成及其生物活性研究 [doctoral dissertation, National Taiwan University]. Airiti Library. https://doi.org/10.6342/NTU.2012.10898
- 蔡紀柔（2015）。亞胺酚基金屬錯合物之合成、結構解析與金屬離子置換反應之研究〔碩士論文，國立暨南國際大學〕。華藝線上圖書館。https://doi.org/10.6837/NCNU.2015.00270
- Lin, G. (1996). The chemistry of organolanthanide complexes containing functionalized phosphine ligands [doctoral dissertation, The University of Hong Kong]. Airiti Library. https://www.airitilibrary.com/Article/Detail?DocID=U0029-1812201200007039
- Peng, Y., Zhang, M. M., Chen, Z. F., Hu, K., Liu, Y. C., Chen, X., & Liang, H. (2013). Synthesis, Characterization, and Interaction with Biomolecules of Platinum(II) Complexes with Shikimic Acid-Based Ligands. Bioinorganic Chemistry and Applications, 2013(), 36-47. https://doi.org/10.1155/2013/565032