LiFePO_4-based cathode materials have been recognized as one of the most promising cathode materials for lithium-ion batteries used in electricity storage systems of various power tools, hybrid/pure electrical vehicles, and stationary applications due to their excellent cycling performance, environmental benign, higher reaction temperature with electrolyte, higher overcharging tolerance, and potentially lower cost than other cathode materials. The developments on LiFePO_4-based materials in our research center and the results obtained recently will be presented in this paper.