摘要
鈷金屬在高分子合成上有非常獨特的地位。從1980 年代苯乙烯 (Styrene) 與丙烯酸酯 (Acrylates)的催化鏈轉移聚合反應 (Catalytic chain transfer polymerization)到近年醋酸乙烯酯 (Vinyl acetate) 與非共軛單體 (unconjugated monomers) 的可控/活性自由基聚合 (Controlled/living radical polymerization)，鈷的錯合物都展現了其特殊的反應性。在這篇回顧文獻中，我們將介紹有機鈷金屬錯合物在高分子合成中的歷史背景，反應機理，與目前發展的情形。並在文末對這領域未來可能的發展方向提出建議。
並列摘要
Cobalt complexes, which areunique species in the field of polymer synthesis, have demonstrated an extraordinary reactivity in catalytic chain transfer (CCT) polymerization of styrene and acrylates since 1980s and also recently for controlled/living radical polymerization (C/LRP) of vinyl acetate and other unconjugated monomers. In this review, we will introduce the background, reaction mechanism, and current status of the polymerization mediated by cobalt complexes. The perspective of this field will also be covered at the end of this article.
延伸閱讀
- Lai, H. Y. (2021). 多功能鈷金屬錯合物之合成及應用 [master's thesis, National Taiwan University]. Airiti Library. https://doi.org/10.6342/NTU202101891
- Liang, Y. R. (2009). 有機金屬可逆性加成裂解鏈轉移劑的合成與聚合應用 [master's thesis, Tatung University]. Airiti Library. https://www.airitilibrary.com/Article/Detail?DocID=U0081-3001201315104496
- Yang, K. H. (2012). 一價釕金屬錯合物的合成與反應性的研究 [master's thesis, National Tsing Hua University]. Airiti Library. https://doi.org/10.6843/NTHU.2012.00237
- Liang, H. Y. (2015). 有機金屬錯合物在開環與可控/活性自由基聚合的應用 [doctoral dissertation, National Tsing Hua University]. Airiti Library. https://doi.org/10.6843/NTHU.2015.00092
- 王富生、彭之皓（2020）。Cobalt Complexes in Radical Polymerization。化學，78(4)，239-249。https://doi.org/10.6623/chem.202012_78(4).004