Determination of Equilibrium and Kinetic Parameters of the Adsorption of Cr(III) and Cr(VI) from Aqueous Solutions to Agave Lechuguilla Biomass.

Jaime Romero-González ； Jorge L. Gardea-Torresde ； José R. Peralta-Videa ； Elena Rodriguez

《Bioinorganic Chemistry and Applications》 2005卷 (2005/12) Pp. 55-68

https://doi.org/10.1155/BCA.2005.55

摘要

This investigation reveals the capability of Agave lechuguilla for trivalent and hexavalent chromium removal from aqueous solutions. Experimentation included pH profile, time dependence, adsorption capacity (K_F and Q_L), adsorption intensity (n and R_L) and saturation capacity (q_s) studies. Batch experiments were conducted at 22℃ to characterize and model the adsorption equilibrium as well as biomass adsorption rates. pH 4 was the optimum for Cr(III) binding, while Cr(VI) optimum binding was at pH 2. Time profile experiments indicated that the adsorption of Cr(VI) by lechuguilla biomass was time-dependent and that of Cr(III) was not. Kinetic models demonstrated that a pseudo-second order reaction model best described the kinetic data for Cr(VI). The adsorption isotherms showed that the binding pattern for Cr(VI) followed the Freundlich isotherm model, while that for Cr(lll) followed the Langmuir isotherm.

關鍵字

Adsorption ； Cr(III) ； Cr(VI) ； kinetic ； equilibrium ； lechuguilla