The characteristics o f lithology, mineral and geochemistry demonstrate that over ten layers of light color clay beds within phosphatic sequence of the Early Cambrian Meishucunian Stage in eastern Yunnan are volcanogenic metabentonites. These metabentonites representing volcanic eruption events are important isochronous markers for stratigraphic correlation of the area. Metabentonites retain high concentrations of relatively immobile trace elements, particularly Hf, Nb, Y., Th and U in comparison with non-volcanogenic mudstone, and contain elss concentrations of Fe, Ni, Co and Cr that those of the mudstone of the Yu'anshan Formation, TiO_2/AI_2O_3, Ti/Th and Zr/Hf ratios of all metabentonites suggest characteristic of acidic magmas. Both chondrite-normalized REE distribution patterns and middle to large Eu negative anomalies of the metabentonites are similar to those of granites. The temporal and spatial distributions of the metabentonites indicate that volcanic activities occurred frequently during the Early Cambrian Meishucunian Stage. These volcanic eruption events could be related to the separation of an old continent and extension in a intra-plate setting.