Light Emitting Diodes (LEDs) have been used in daily life broadly, such as traffic light, signboard display, etc.. Recently, it has been the trend applied LEDs for backlight source of the cellular phones. Refer to this, we could forecast that LEDs would take the place of traditional light sources and turn into backlight source of the large-size display panels. Moreover, it might be the mainstream as daily illumination system in the future. As the current is getting higher and higher, we can infer from the formula, Ρ=Ι^2×R, the more and more energy will transfer to the heat. However, LEDs are the devices that are not heat-resistant. When the temperature between the PN junction is above the rated temperature, the transfer efficiency from input power to light will decrease rapidly. Then, the whole system will be in a status of positive feedback. Finally, LEDs will burn due to overheatness. Accordingly, to solve the issue about the heat is indeed the need. In my research, to choose appropriate material for package, and to testify the relation between parameters and temperatures are the major topics in order to manage the thermal problem when the LED is overheated. Base on recent reports, using silicon as the substrate which LED die placed on can lower the thermal resistance as a whole due to good thermal conductivity. By the way, because the silicon is non-metal material, the thermal expansion coefficient does match better that of the LED’s. In case of high temperature, the thermal stress and the deformation will be much smaller compared to using metal materials. Moreover, when it comes to multi-chip, pairs of electrodes can be fulfilled by some means directly in silicon or non-metal substrate. Consequently, it is good for enhancing the reliability of the LED package by using silicon substrate.