- 學位論文
利用準分子牢籠自富勒烯萃取物中分離純化C60
Using Hemicarceplex to Isolate High Purity C60 Directly From Fullerene Extract
若您是本文的作者，可授權文章由華藝線上圖書館中協助推廣。
摘要
我們合成了一個可與C60形成室溫下可被分離之活門囚籠錯合物(hemicarceplex)之分子牢籠。利用此一分子，我們可以自市售之富勒烯萃取物(fullerene extract)中直接分離純化出純度≥98%之C60，毋須經過液相層析或再結晶的程序。
關鍵字
囚籠錯合物並列摘要
A cyclotriveratrylene-based molecular cage that favors the formation of a room temperature isolable C60-incarcerated hemicarceplex had been synthesized. Significant differences in the association and dissociation kinetics of the molecular cage and fullerenes allowed the isolation of C60 in high purity (≥98.0%) from a commercial fullerene extract without the need for recrystallization or HPLC.
並列關鍵字
Hemicarceplex參考文獻
1. Lehn J. M. Supramolecular Chemistry, VCH: Weinhein, 1995.
3. Atwood J. L. (Ed.) Inclusion Phenomena and Molecular Recognition Plenum Press:New York, 1998.
6. Robinson, G. M. J. Chem. Soc., Trans. 1915, 107, 267.
8. Erdtman, H.; Haglid, F.; Ryhage, R. Acta Chem. Scand. 1964, 18, 1249.
9. Goldup, A.; Morrison, A. B.; Smith, G. W. J. Chem. Soc. 1965, 3864.
延伸閱讀
- 王凱平（2014）。探討以活性碳進行萃取式發酵來提升Clostridium acetobutylicum 產丁醇之研究〔碩士論文，國立中央大學〕。華藝線上圖書館。https://www.airitilibrary.com/Article/Detail?DocID=U0031-0412201512023903
- 王星翰（2018）。纖維電噴灑游離質譜法結合線上微萃取濃縮技術對嘉磷塞的分析與研究〔碩士論文，國立臺灣師範大學〕。華藝線上圖書館。https://doi.org/10.6345/THE.NTNU.DC.005.2018.B05
- Hadjmohammadi, M. R., & Sharifi, V. (2007). 利用固相萃取淨化及預濃縮方式前處理並以HPLC-UV、UV及原子吸收光譜檢測複合維他命錠劑中維生素B12. 藥物食品分析, 15(3), 285-289. https://www.airitilibrary.com/Article/Detail?DocID=10219498-200709-15-3-285-289-a
- 郭培龍、鄭建鴻（1994）。Inorganic Chemistry of Fullerene。化學，52(1)，37-42。https://doi.org/10.6623/chem.1994006
- 張有文（1992）。Research of Fullerene-60 synthesis method and separation y〔碩士論文，元智大學〕。華藝線上圖書館。https://www.airitilibrary.com/Article/Detail?DocID=U0009-0112200611300350