Experiments make suspended droplets include binary fuels of different boiling point , and observe characteristics of the combustion. The binary fuel mixtures used in this experiment were biodiesel/soybean oil, biodiesel/corn oil, biodiesel/ grapeseed oil, and biodiesel/ ethanol. This experimental results showed the variation of micro-explosion and flame shrinkage were slight , because the property of biodiesel and soybean oil were similar. After the micro-explosion of droplet , it still keep spherical symmetry on combustion ,when boiling point of bio oil and bio diesel were similar. Biodiesel/ ethanol fuel on different heating temperature will cause varied status , after the micro-explosion of droplet , it will burst and become numerous extinction little droplets , when boiling point of ethanol and bio diesel were different.