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  • 學位論文

以CTV為基礎之籠狀分子與銨鹽的錯合研究

The Complexation of a CTV-Based Molecular Container to Tetra-alkyl Ammonium Salts

指導教授 : 邱勝賢

摘要


運用實驗室先前發展出來之CTV為基礎的分子容器合成策略,合成以dibenzo-30-crown-10為架構之CTV分子容器。將分子容器與適當之客體分子做錯合的研究,從NMR氫譜上可以看到明顯之化學位移改變,可推測我們的分子容器對此客體分子有錯合之作用。

並列摘要


We have synthesized the cyclotirveratrylene molecular container based on dibenzo-30-crown-10 using the method we developed before. We studied the complex character between the molecular container and appropriate guest molecule. It showed that the chemical shift of the 1H-NMR spectra moved obviously. We supposed there were some interaction between our molecular container and the guest molecule.

參考文獻


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