- 學位論文
利用碘化銅及雙胺配基催化醯亞胺與芳香基鹵化物之碳-氮鍵偶合反應
Copper-Diamine-Catalyzed N-Arylation of Imide
並列摘要
N-aryl imides can be synthesized with catalytic amount of copper (I) iodide, potassium phosphate, and N,N'-dimethylcyclohexane-1,2-diamine as a ligand at 140 oC under neat condition. By this method, phthalimide can be coupled with various aryl halides in good yields, and we can obtain mono substitution products as coupling with aryl dibromides or aryl tribromides. A general method for mild, rapid, efficient C-N bound coupling reaction was established from this research.
參考文獻
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延伸閱讀
- 莊智超（2007）。鹵化銅催化2-(2-取代基-1-炔基)-氮,氮二甲基苯胺之環化反應：合成三鹵吲哚〔碩士論文，高雄醫學大學〕。華藝線上圖書館。https://doi.org/10.6832/KMU.2007.00117
- 鄭惠文（2016）。可用於親核性芳香環氟化反應之不對稱雙苯基碘鹽的合成研究〔碩士論文，國立臺灣大學〕。華藝線上圖書館。https://doi.org/10.6342/NTU201603126
- 林俊甫（2016）。碘化亞銅與三牙吡啶配位基之配位化合物合成〔碩士論文，國立中正大學〕。華藝線上圖書館。https://www.airitilibrary.com/Article/Detail?DocID=U0033-2110201614062808
- Ganesan, B. (2020). Copper-Catalyzed Synthesis of N-heterocycles Using DMF as Benign C1 and N1 Synthon [doctoral dissertation, Kaohsiung Medical University]. Airiti Library. https://www.airitilibrary.com/Article/Detail?DocID=U0011-1502202018021300
- 謝孟諠（2016）。Copper Catalyst for the Synthesis of Various Aryl Amido Furans and Hydroxyisoindolinone Derivatives〔碩士論文，國立臺灣師範大學〕。華藝線上圖書館。https://doi.org/10.6345/NTNU202204736