金屬−配基自組裝分子膠囊之配基引入具液晶性質結構之合成及研究

Synthesis and Research of Metal−ligand Self-assembled Molecular Capsule. Ligand Introduced Liquid Crystal Property Structure

高韋鋐(Wei-Hung Kao)

指導教授 ： 徐秀福

淡江大學/理學院/化學學系碩士班/碩士(2022年)

https://doi.org/10.6846/TKU.2022.00580

摘要

在本論文中結合金屬−配基自組裝以及液晶性質結構設計出具有多功能性的分子膠囊，配基使用兩個間位吡啶配基與金屬配位後夠產生一個四配位的分子孔洞，此孔洞直徑約為1 nm，依照參考文獻此孔洞能夠容納C60。配基引入具液晶性質的結構，預期此分子膠囊捕捉客體分子後能夠透過偏光顯微鏡快速了解主客間的作用狀態。

關鍵字

自組裝 ； 分子膠囊 ； 液晶 ； 富勒烯

並列摘要

We utilized metal¬ligand self-assembled and liquid crystal conceptions designed a multifunction molecular capsule. Bi-pyridine on the ligand coordinate with metal will form a four-coordinate molecular capsule. The diameter of the capsule is approx. 1nm. Refer to literature this hole can capture a C60.We expected liquid crystal capsule capture guest molecule could be observed simply and quickly by polarized optical microscopy.

並列關鍵字

self-Assembled ； molecular capsule ； liquid crystal ； fullerene

參考文獻

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