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  • 學位論文

染料敏化太陽能電池製作及性質

Manufacturing and Properties of Dye-Sensitized Solar Cell

指導教授 : 林清彬

摘要


本研究係以溶膠凝膠法配製TiO2溶液,並利用旋轉塗佈機將其塗佈在ITO導電玻璃上,製作成一多孔性薄膜電極。以不同熱處理溫度及不同塗佈層數之TiO2薄膜來探討溫度、膜厚分別對轉換效率的影響,在650℃/三層TiO2薄膜之染料敏化太陽電池其轉換效率達到1.71 %。在碘濃度為0.1M時為此實驗電解液之最佳參數,另外TiO2薄膜電極通過4-叔丁基吡啶的處理,染料敏化太陽能電池之轉換效率較未處理電極高出了13%。

並列摘要


The TiO2 solution was made by sol-gel method in this research. The mesoporous TiO2 film was grown on ITO glass by spin coater via layer-by-layer deposition. The influence of heat treatment temperature and TiO2 film thickness on conversion efficiency was discussed here. The conversion efficiency of DSSC with three-layers TiO2 film treated at 650℃ is 1.71 %. 0.1M of iodide was optimized parameter of electrolyte in this research. Furthermore, the TiO2 film gave a higher conversion efficiency than the TiO2 film nontreated by 4-tertbutylpyridine, which increased 13% by surface treatment with 4-tertbutylpyridine.

參考文獻


4. U. Gangopadhyay, K.H. Kim, S.K. Dhungel, U. Manna, P.K. Basu, M.
for large area commercial mono-crystalline silicon solar cells〞Solar
Lévy-Clément〝Multicrystalline silicon solar cells with porous silicon
emitter〞Solar Energy Material & Solar Cells, vol.60, No.4(2000)pp.
amorphous silicon thin film transistor fabricated at 125 °C by DC

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