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  • 學位論文

氮化鎵系發光二極體之銀/氧化銦鋅反射式電極的研製

Study of Reflective Ag/Zinc Oxide Doped Indium Oxide Ohmic Contacts for Flip Chip GaN LED Applications

指導教授 : 陳隆建
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摘要


本篇論文研究將針對在p型氮化鎵(p-GaN)材料上進行銀與銀/氧化鋅摻雜氧化銦(ZIO)之高反射率歐姆接觸電極,並應用於發光二極體元件。銀反射電極在大氣環境下,經過300 ℃退火10分鐘,特徵電阻值約為 5×10-3 Ωcm2 。將銀反射電極應用於發光二極體上,起始電壓為3.55 V(@20 mA)。銀/氧化鋅摻雜氧化銦(ZIO)之反射電極在大氣環境下,經過500 ℃退火10分鐘,特徵電阻值約為1.74×10-4 Ωcm2 。當其應用於發光二極體上,在室溫環境,起始電流20 mA之下,量測其起始電壓為3.15 V,而光輸出功率與功率效率分別為7.86 mW與12.44 %。證實了使用氧化鋅摻雜氧化銦(ZIO)當披覆層,有效提升了其熱穩定性,搭配銀反射電極成為高反射率歐姆接觸電極,提升了發光二極體效能。本研究採用化學分析電子儀來探討其歐姆接觸的機制。

並列摘要


Ag and Ag/ZIO schemes for the formation of low resistance and highly reflective ohmic contacts to p-GaN for flip-chip light emitting diodes were investigated.The Ag contacts show good ohmic characteristics with contact resistivity of 5×10-3 Ωcm2 when annealed at 300 ℃ for 10 min in vacuum. LEDs fabricated using the Ag contacts layers give forwardbias voltages of 3.55V at 20 mA.The Ag/ZIO contacts show better ohmic characteristics with contact resistivity of 1.74×10-4 Ωcm2 when annealed at 500 ℃ for 10 min in vacuum. LEDs fabricated using the Ag/ZIO contacts layers give forwardbias voltages of 3.15 V at 20 mA.A light output power and an Power efficiency of the LED with Ag/ZIO contact of 7.86 mW and 12.44 %, resoectuvely, are measured at a forward current of 20 mA at room temperature. It is clearly shown that a transparent contact overlayer is necessary to make high-quality ohmic contacts to p-type GaN for thermally stable flip-chip LEDs using Ag reflectors.Based on electron spectroscopy for chemical analysis (ESCA), possible ohmic formation mechanisms are discussed.

參考文獻


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